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Desmond Clark (1979) wrote that were it not for radiocarbon dating, "we would still be foundering in a sea of imprecisions sometime bred of inspired guesswork but more often of imaginative speculation" (Clark, 1979:7).
They chose samples whose age could be independently determined.
These isotopes are present in the following amounts C12 - 98.89%, C13 - 1.11% and C14 - 0.00000000010%.
Thus, one carbon 14 atom exists in nature for every 1,000,000,000,000 C12 atoms in living material.
The radiocarbon method was developed by a team of scientists led by the late Professor Willard F.
Libby of the University of Chicago in immediate post-WW2 years.
A sample of acacia wood from the tomb of the pharoah Zoser (or Djoser; 3rd Dynasty, ca. Libby reasoned that since the half-life of C years, they should obtain a C14 concentration of about 50% that which was found in living wood (see Libby, 1949 for further details).
The results they obtained indicated this was the case.
There is a quantitative relationship between the decay of 14C and the production of a beta particle. That is, the probability of decay for an atom of 14C in a discrete sample is constant, thereby requiring the application of statistical methods for the analysis of counting data.
It follows from this that any material which is composed of carbon may be dated.
The half-life () is the name given to this value which Libby measured at 556830 years. After 10 half-lives, there is a very small amount of radioactive carbon present in a sample.
At about 50 - 60 000 years, then, the limit of the technique is reached (beyond this time, other radiometric techniques must be used for dating).
As 14C decays it emits a weak beta particle (b ), or electron, which possesses an average energy of 160ke V.